Synthesis and Characterization of NaCMC/HEC/ Activated Carbon Hydrogel Composites for the Desalination of Seawater*

Johndel Obra

Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, Philippines, 1101;

Corresponding Author: jbobra02@gmail.com

James Quin Maranan

Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, Philippines, 1101;

Corresponding Author: james.maranan.512@gmail.com

Denise Faye Lensoco

Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, Philippines, 1101;

Corresponding Author: denisefayeg@gmail.com

Terence Tumolva

Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, Philippines, 1101;

Corresponding Author: tptumolva@up.edu.ph

Abstract :

Current available methods for water desalination are energy intensive, expensive, and not feasible for small-scale applications. As an alternative, hydrogels and hydrogel composites may be utilized both as draw agent and semi-permeable membrane to desalinate water via forward osmosis. In this study, a non-toxic, biodegradable, and low-cost hydrogel composite is prepared by adding activated carbon (AC) as filler to a 3:1 blend of sodium carboxymethyl cellulose (NaCMC) and hydroxyethyl cellulose (HEC), with citric acid as crosslinking agent. A one factor-at-a-time (OFAT) analysis was performed to correlate the crosslinker concentration, crosslinking duration, and AC content to the swelling and desalination efficiency of the CMC/HEC/AC hydrogel composite. Results showed that the swelling of the hydrogel varies directly with the crosslinking duration but varies inversely with the crosslinking concentration. The experiments also showed that the addition of AC as filler significantly improves the desalination efficiency of the hydrogel composite; however, it was also observed that efficiency is reduced if the AC content is excessive.

Keywords:
  • hydrogel,
  • composite,
  • desalination,
  • activated carbon,
  • cellulose
Reference

[1] Thimmarajum M., et al., Desalination of water. Desalination and Water Treatment, online available from https://www.intechopen.com/chapters/63043

[2] Barron, O., et al., “Desalination techniques- a review of the opportunities for desalination in agriculture,” Desalination, vol. 364, pp. 2-16, 2015.

[3] Campos C, The Economics of Desalination for Various Uses, available online: http://www.rac.es/ ficheros/doc/00731.pdf

[4] Majcher K, How Can Desalination Become Cheaper?, available online: https://www.technologyreview. com/ 2014/12/03/170231/how-can-desalination-become-cheaper

[5] Boden K S and Subban, C V, A road map for small-scale desalination: An overview of existing and emerging technology solutions for cost-efficient and low-energy desalination in South and Southeast Asia, available online: https://www.ctc-n.org/sites/www.ctc-n.org/files/resources/roadmap_for_small-scale_ desalination_southeast_asia.pdf

[6] Li, D., et al., “Forward osmosis desalination using polymer hydrogels as a draw agent: influence of draw agent, feed solution and membrane on process performance,” Water Research, vol. 47, no. 1, pp. 209-215, 2013.

[7] Akther, N., et al., “Recent advancements in forward osmosis desalination: A review,” Chemical Engineering Journal, vol. 281, pp. 502-522, 2015.

[8] Zheng, W. J., et al., “Facile fabrication of self-healing carboxymethyl cellulose hydrogels,” European Polymer Journal, vol. 72, pp. 514-522, 2015”.

[9] Akalin, G. O. and Pulat, M., “Preparation and characterization of nanoporous sodium carboxymethyl cellulose hydrogel beads,” Journal of Nanomaterials, vol. 2018, pp. 1-12, 2018.

[10] Ambrosio, L., et al., “Novel superabsorbent cellulose-based hydrogels crosslinked with citric acid,” J. App. Polym. Sci., vol. 110, no. 4, pp. 2453-2460, 2018.

[11] Hu, S. and Qiu, X., “Smart materials based on cellulose: a review of the preparations, properties, and applications,” Materials, vol. 6, no. 3, pp. 738-781, 2013.

[12] Tumolva, T., et al., “Developing a HEC/CMC-reduced graphene oxide hydrogel nano-composite for seawater desalination,” Solid State Phenomena, vol. 324, pp. 173-178, 2021.

[13] Sweetman, M. J., et al., “Activated carbon, carbon nanotubes and graphene: materials and composites for advanced water purification,” Journal of Carbon Research, vol. 3, no. 18, 2017.

[14] Mali, K. K., et al., “Citric acid crosslinked carboxymethyl cellulose-based composite hydrogel films for drug delivery,” Indian J. Pharm. Sci., vol. 80, no. 4, 2018

[15] Li, J. et al., “Effect of activated carbon on the properties of carboxymethylcellulose/activated carbon hybrid hydrogels synthesized by γ-radiation technique,” Carbohydrate Polymers, vol. 70, no. 2, pp. 236-242, 2007

© The Author(s), under exclusive license to Technoarete Publishers 2022
About this Paper
Cite this paper

Johndel Obra, James Quin Maranan, Denise Faye Lensoco, Terence Tumolva. (2022). Synthesis and Characterization of NaCMC/HEC/ Activated Carbon Hydrogel Composites for the Desalination of Seawater. In: Dr Sunita Singh, Dr Mohammed Aurifullah, Dr. Peiman Kianmehr, Dr. Monica Dragomirescu, Smart Environmental Science Technology and Management. Lecture Notes on Environment Conservation and Enrichment, vol 1. Technoarete Publishers. doi.org/10.36647/978-93-92106-02-6.16

Publisher Name

Technoarete Publishers

ISBN

978-93-92106-02-6

DOI

doi.org/10.36647/978-93-92106-02-6.16

  • ISBN - 978-93-92106-02-6
  • Instant PDF download
  • Readable on all devices
  • Total No. of. Pages - 150
  • Available to everyone
  • Free Access
doi.org/10.36647/978-93-92106-02-6.16

Full
Paper