Desorption of Lead Ions from Used Sodium Alginate-Hydroxypropyl Cellulose Adsorbent Beads

Rodel D. Guerrero

Department of Chemical Engineering and Technology, College of Engineering and Technology, MSU-Iligan Institute of Technology, Iligan City, Philippines, 9200

Corresponding Author: rodel.guerrero@g.msuiit.edu.ph

Abstract :

Efficient removal of adsorbed lead ions from the sodium alginate-hydroxypropyl cellulose beads was necessary to guarantee their long-term use for repeated adsorption-desorption cycles. In this study, the desorption characteristics of previously adsorbed lead ions on sodium alginate-hydroxypropyl (SA-HPC) cellulose adsorbent beads were tested using various eluents such as sulfuric acid and ethylenediaminetetraacetic acid (EDTA). SA-HPC adsorption beads were produced using 3:1 ratio of sodium alginate to hydroxypropyl cellulose via ionotropic gelation. Generally, using H2SO4 as eluent maintained an exceptional adsorption efficiency throughout in each cycle, but showed a weak desorption efficiency performance. The desorption efficiency using 0.1M EDTA, on the other hand, was found to be the most effective but resulted to the beads disintegration after the first cycle.

Keywords:
  • sodium alginate ,
  • hydroxypropyl cellulose ,
  • adsorption ,
  • desorption ,
  • eluent ,
  • lead
Reference

[1] Y.C. Sharma Economic Treatment of Cadmium(II)-Rich Hazardous Waste by Indigenous Material. J. Colloid Interfac. Sci., vol. 173, pp. 66-70, 1995.

[2] E.W. Wilde, and J.R. Benemann. Bioremoval of heavy metals by the use of microalgae. Biotechnol Adv. 1993;11(4):781-812. doi: 10.1016/0734-9750(93)90003-6. PMID: 14538057.

[3] F. Veglio, and F. Beolchini. Removal of Metals by Biosorption: A Review. Hydrometallurgy, 44, 301-316, 1997. http://dx.doi.org/10.1016/S0304-386X(96)00059-X

[4] D. Kratochvil, and B. Volesky, B. Biosorption of Cu from Ferruginous Wastewater by Algal Bio-mass. Water Research, 32, 2760-2768, 1998.

[5]. B. Volesky. Detoxification of metal-bearing effluents: biosorption for the next century. Hydrometallurgy, vol. 59, Issues 2–3, pp. 203-216, 2001. https://doi.org/10.1016/S0304-386X(00)00160-2.

[6] S. Shamim. Biosorption of Heavy Metals. InTech Open, 2018. doi: 10.5772/intechopen.72099

[7] G. Gadd. Metals, minerals and microbes: geomicrobiology and bioremediation. Microbiology, vol. 156, pp. 609-643, 2010.

[8] R. Sudha Bai, and T. Emilia Abraham. Biosorption of Cr (VI) from aqueous solution by Rhizopus nigricans. Bioresource Technology, vol. 79, Issue 1, pp. 73-81, 2001.https://doi.org/10.1016/S0960 8524(00)00107-3.

[9] C.M. Alarde, R. Guerrero, C. Acibar, J. Maslog, and C.J. Pacilan. Evaluation of Pb (II) Removal from Water Using Sodium Alginate/Hydroxypropyl Cellulose Beads. E3S Web Conf. 148 02002, 2020. DOI: 10.1051/e3sconf/202014802002

[10] H. Zhao, X. Ouyang, and L. Yang. Adsorption of lead ions from aqueous solutions by porous cellulose nanofiber–sodium alginate hydrogel beads. Journal of Molecular Liquids, 2020. doi: 10.1016/j.molliq.2020.115122

[11] J. Delaney, A. Liberski, J. Perelaer, and U. Schubert. Reactive inkjet printing of calcium alginate hydrogel porogens - A new strategy to open-pore structured matrices with controlled geometry. The Royal Society of Chemistry, 2010. doi: 10.1039/B922888H

[12] A. Petrovic, and M. Simonic. Removal of heavy metal ions from drinking water by alginate-immobilised Chlorella sorokiniana. International journal of Environmental Science and Technology, 2016(13), 1761 1780. doi: 10.1007/s13762-016-1015-2

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Rodel D. Guerrero, Imee Kassandra E. Cacho, Dan Michael A. Asequia, Joshua Emmanuel L. Hugo. (2022). Desorption of Lead Ions from Used Sodium Alginate-Hydroxypropyl Cellulose Adsorbent Beads. In: Dr Sunita Singh, Dr Mohammed Aurifullah, Dr. Peiman Kianmehr, Dr. Monica Dragomirescu, Smart Environmental Science Technology and Management. Lecture Notes on Environment Conservation and Enrichment, vol 1. Technoarete Publishers. doi.org/10.36647/978-93-92106-02-6.7

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doi.org/10.36647/978-93-92106-02-6.7

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